How can the acidity of shampoo affect hair?

Hair has its own natural pH (acidity/alkalinity) balance, just like skin — and keeping it in the right range is key for shine, smoothness, and strength.

🌿 Natural Hair pH

  • Hair shaft (the strand): about 3.6–5.5
  • Scalp: about 4.5–5.5
    ➡️ Both are slightly acidic, which helps keep the cuticle (outer layer) closed and smooth, protecting hair from dryness and frizz.

💧 How pH affects your hair

pH level

Effect on hair

Acidic (3–5.5)

Smooths and tightens the cuticle → shiny, frizz-free hair. Maintains moisture and strength.

Neutral (~7)

Can start to open the cuticle slightly — not ideal for frequent use.

Alkaline (8–10)

Lifts the cuticle, allowing moisture to escape → dryness, dullness, and breakage. Common in soaps and chemical treatments.


🧴 Typical pH ranges of hair products

Product

Ideal pH range

Notes

Shampoos

4.5 – 6.5

pH-balanced or “acidic” shampoos help keep the cuticle smooth and scalp healthy.

Conditioners

3.5 – 5.5

Slightly more acidic to seal the cuticle after washing.

Leave-in treatments

4 – 5

Maintains hydration and reduces static.

Hair dyes / relaxers / perms

8 – 11+

Very alkaline — opens cuticle for color or texture changes; should always be neutralised afterward.

Apple cider vinegar rinses

~2.5 – 3.5

Very acidic — can help close the cuticle, but overuse can dry or irritate scalp. Dilute before use.


How to maintain healthy hair pH

  1. Use pH-balanced shampoos (labelled ~5 or “acidic”).
  2. Avoid harsh alkaline products, especially bar soaps or baking soda.
  3. Rinse with cool water — helps seal the cuticle naturally.
  4. Use conditioner every wash to rebalance pH after cleansing.
  5. Limit chemical treatments or follow with a neutralising conditioner.

That's why my solid shampoo and conditioner is 5, not all shampoos are, so check before you buy!

Solid Shampoo & Conditioner Duo – Marigold Charms

Happy Beauty!

Marionx

 

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